|
|
MATERIAL SAFETY DATA SHEET 2007-01-01
SECTION 1: PRODUCTS AND MANUFACTURE
Product: Valve Regulated Lead Acid Battery (VRLA Battery)
Manufacturer:
NARADA POWER SOURCE CO., LTD.
No. 459 Wensan Road
Hangzhou P.R.China Zip Code: 310013
Tel:(+86-571) 28827012 / 28827013 Fax:(+86-571) 85126942
Email: intl@narada.biz Website: www.naradabattery.com
Product:
COMMERCIAL NAME
BATTERIES WITH ABSORBED ELECTROLYTE WET, NON-SPILLABLE
TECHNICAL NAME
BATTERIES CONTAINING A SOLUTION OF SULPHURIC ACID AND DISTILLED WATER, ABSORBED IN SEPARATORS
SECTION 2: HAZARDOUS COMPONENTS
COMPONENTS |
%WEIGHT |
TLV |
LD50 ORAL |
LC50 INHALATION |
LC50 CONTACT |
Lead (Pb, PbO2, PbSO 4) |
About 70% |
- |
(500) mg/Kg |
- |
- |
Sulfuric Acid DILUTED SULPHURIC ACID ¨C H2SO4 |
About 20% |
1 mg/m3 |
(2.140) mg/Kg |
- |
- |
Fiberglass Separator |
About 5% |
- |
- |
- |
- |
ABS or PP |
About 5% |
- |
- |
- |
- |
SECTION 3: PHYSICAL DATA
COMPONENTS |
DENSITY |
MELTING POINT |
SOLLUBILITY (H 20) |
ODOR |
APPEARANCE |
Lead |
11.34 |
327.4oC (Boiling) |
None |
None |
Sliver-Gray Metal |
Lead Sulfate |
6.2 |
1070oC (Boiling) |
40 mg/l ( 15oC) |
None |
White Powder |
Lead Dioxide |
9.4 |
290oC (Boiling) |
None |
None |
Brown Powder |
Sulfuric Acid |
About 1.3 |
About 114oC (Boiling) |
100% |
Acidic |
Clear Colorless Liquid |
Fiberglass Sep. |
- |
- |
SLIGHT |
TOXIC |
WHITE FIBROUS GLASS |
ABS or PP |
- |
- |
NONE |
NO ODOR |
SOLID |
SECTION 4: PROTECTION
EXPOSURE |
PROTECTION |
COMMENTS |
SKIN |
Rubber gloves, Apron, Safety shoes |
Protective equipment must be worn if battery is cracked or otherwise damaged. |
RESPIRATORY |
Respirator (for lead) |
A respirator should be worn during reclaim operations if the TLV exceeded. |
EYES |
Safety goggles, Face Shield |
|
SECTION 5: FLAMMABILITY DATA
COMPONENTS |
FLASHPOINT |
EXPLOSIVE LIMITS |
COMMENTS |
Lead |
None |
None |
|
Sulfuric Acid |
None |
None |
|
Hydrogen |
259oC |
4% - 74.2% |
Sealed batteries can emit hydrogen only if over charged (float voltage> 2.4 VPC). The gas enters the air through the vent caps. To avoid the chance of a fire or explosion, keep sparks and other sources of ignition away from the battery.
Extinguishing Media: Dry chemical, foam, CO 2 |
Fiberglass Sep. |
- |
- |
Toxic vapors may be released.
In case of fire: wear self-contained breathing apparatus. |
478 Polystyrene |
None |
- |
Temperatures over 300 oC ( 572oF) may release combustible gases. In case of fire: wear positive pressure self-contained breathing apparatus. |
SECTION 6: REACTIVITY DATA
COMPONENT |
Lead/lead compounds |
STABILITY |
Stable |
INCOMPATIBILITY |
Potassium, carbides, sulfides, peroxides, phosphorus, sulfurs. |
DECOMPOSITION PRODUCTS |
Oxides of lead and sulfur. |
CONDITIONS TO AVOID |
High temperature, Sparks and other sources of ignition. |
COMPONENT |
Sulfuric Acid |
STABILITY |
Stable at all temperatures |
POLYMERIZATION |
Will not polymerize |
INCOMPATIBILITY |
Reactive metals, strong bases, most organic compounds |
DECOMPOSITION PRODUCTS |
Sulfuric dioxide, trioxide, hydrogen sulfide, hydrogen |
CONDITIONS TO AVOID |
Prohibit smoking, sparks, etc. from battery charging area. Avoid mixing acid with other chemicals. |
SECTION 7: CONTROL MEASURES
1. Store lead/acid batteries with adequate ventilation. Room ventilation is required for batteries utilized for standby power generation. Never recharge batteries in an unventilated, enclosed space.
2. Do not remove vent caps. Follow shipping and handling instructions that are applicable to the battery type. To avoid damage to terminals and seals, do not double-stack industrial batteries.
STEPS TO TAKE IN CASE OF LEAKS OR SPILLS
If sulfuric acid is spilled from a battery, neutralize the acid with sodium bicarbonate (baking soda), sodium carbon (soda ash), or calcium oxide (lime).
Flush the area with water discard to the sewage systems. Do not allow unneutralized acid into the sewage system.
WASTE DISPOSAL METHOD:
Neutralized acid may be flushed down the sewer. Spent batteries must be treated as hazardous waste and disposed of according to local state, and federal regulations. A copy of this material safety data must be supplied to any scrap dealer or secondary smelter with battery.
ELECTRICAL SAFETY
Due to the battery's low internal resistance and high power density. High levels of short circuit can be developed across the battery terminals. Do not rest tools or cables on the battery. Use insulated tools only.
Follow all installation instruction and diagrams when installing or maintaining battery systems. |
SECTION 8: HEALTH HAZARD DATA
LEAD: The toxic effects of lead are accumulative and slow to appear. It affects the kidneys, reproductive, and central nervous system.
The symptoms of lead overexposure are anemia, vomiting, headache, stomach pain (lead colic), dizziness, loss of appetite, and muscle and joint pain. Exposure to lead from a battery most often occurs during lead reclaim operations through the breathing or ingestion of lead dusts and fumes.
THIS DATA MUST BE PASSED TO ANY SCRAP OR SMELTER WHEN A BATTERY IS RESOLD. |
SULFURIC ACID: Sulfuric acid is a strong corrosive. Contact with acid can cause severe burns on the skin and in the eyes. Ingestion of sulfuric acid will cause GI tract burns. Acid can be release if the battery case is damaged or if the vents are tampered with. |
FIBERGLASS SEPARATOR: Fibrous glass is an irritant of the upper respiratory tract, skin and eyes. For exposure up to 10F/CC use MSA Comfort with type H filter. Above 10F/CC up to 50F/CC use Ultra-Twin with type H filter.
NTP or OSHA does not consider this product carcinogenic. |
SECTION 9: SULFURIC ACID PRECAUTIONS
INHALATION : Acid mist form formation process may cause respiratory irritation, remove from exposure and apply oxygen if breathing is difficult.
SKIN CONTACT : Acid may cause irritation, burns or ulceration. Flush with plenty of soap and water, remove contaminated clothing, and see physician if contact area is large or if blisters form.
EYE CONTACT : Acid may cause severe irritation, burns, cornea damage and blindness. Call physician immediately and flush with water until physician arrives.
INGESTION : Acid may cause irritation of mouth, throat, esophagus and stomach. Call physician. If patient is conscious, flush mouth with water, have the patient drink milk or sodium bicarbonate solution.
DO NOT GIVE ANYTHING TO AN UNCONSCIOUS PERSON. |
SECTION 10: TRANSPORTATION REGULATIONS
We hereby certify that all Narada Battery
Maintenance Free Valve Regulated Lead Acid
Batteries conform to the UN2800 class 8,
classification as " Batteries, wet,
Non- Spillable, and electric storage"
as a result of passing the Vibration and
Pressure Differential Test described in
DOT [49 CFR 173.159(d) and IATA/ICAO Packaging
Instruction 806 [Special Provision A67].
Narada Batteries having met the related
conditions are EXEMPT from hazardous goods
regulations for the purpose of transportation
by DOT, and IATA/ICAO Packaging Instruction
806, and therefore are unrestricted for
transportation by any means. For all modes
of transportation, each battery outer package
is labeled "NON-SPILLABLE". All
our Batteries are marked non-spillable.
|
Manufacturer:
Narada Power Source Co., Ltd.
No. 459 Wensan Road, Hangzhou, China
Tel: +86-571-28827013
Fax: +86-571-85126942
NARADA POWER SOURCE CO., LTD.
MATERIAL SAFETY DATA SHEET
|
|